Near-wall porosity characteristics of fixed beds packed with wood chips

Packed beds of fuel wood chips are commonly found in thermal conversion processes such as combustion or gasification. Wood chips in particular are mostly used as fuel for small-scale domestic heating boilers but also for commercial-scale combustion units. The characterization of spatial voidage distribution inside the wood chip beds is of great importance for flow and reactor modelling. This study focuses on the radial porosity variations of cylindrical beds of three different types of commercially available wood chips including chips classified as G30 size class. The conventional technique of consolidating packed beds with a resin was chosen as the experimental procedure. The radial voidage distribution in different cylindrical beds is determined by image analysis of sections of the solidified packings. Additionally, a packing of monosized spheres was investigated in order to assess the selected procedure in comparison with widely available literature data for spheres. The results are discussed and summarized in a mathematical expression correlating the radial voidage distribution depending on average wood chip size, packing core porosity and dimensionless distance from the tube wall.     

Solving #SAT using vertex covers

We propose an exact algorithm for counting the models of propositional formulas in conjunctive normal form. Our algorithm is based on the detection of strong backdoor sets of bounded size; each instantiation of the variables of a strong backdoor set puts the given formula into a class of formulas for which models can be counted in polynomial time. For the backdoor set detection we utilize an efficient vertex cover algorithm applied to a certain “obstruction graph” that we associate with the given formula. This approach gives rise to a new hardness index for formulas, the clustering-width. Our algorithm runs in uniform polynomial time on formulas with bounded clustering-width. It is known that the number of models of formulas with bounded clique-width, bounded treewidth, or bounded branchwidth can be computed in polynomial time; these graph parameters are applied to formulas via certain (hyper)graphs associated with formulas. We show that clustering-width and the other parameters mentioned are incomparable: there are formulas with bounded clustering-width and arbitrarily large clique-width, treewidth, and branchwidth. Conversely, there are formulas with arbitrarily large clustering-width and bounded clique-width, treewidth, and branchwidth.     

Durability of polymeric glazing materials for solar applications

The economic viability of solar collector systems for domestic hot water (DHW) generation is strongly linked to the cost of such systems. Installation and hardware costs must be reduced by 50% to allow significant market penetration. An attractive approach to cost reduction is to replace glass and metal parts with less expensive, lighter weight polymeric components. Weight reduction decreases the cost of shipping, handling, and installation. The use of polymeric materials also allows the benefits and cost savings associated with well established manufacturing processes, along with savings associated with improved fastening, reduced part count, and overall assembly refinements. A key challenge is to maintain adequate system performance and assure requisite durability for extended lifetimes. Results of preliminary and ongoing screening tests for a large number of candidate polymeric glazing materials are presented. Based on these results, two specific glazings with moderate and poor weathering stability are selected to demonstrate how a service lifetime methodology can be applied to accurately predict the optical performance of these materials during in-service use. A summary is given for data obtained by outdoor exposure and indoor testing of polyvinyl chloride (PVC) and high temperature modified polycarbonate copolymer (coPC) materials, and an initial risk analysis is given for the two materials. Screening tests and analyses for service lifetime prediction are discussed. A methodology that provides a way to derive correlations between degradation experienced by materials exposed to controlled accelerated laboratory exposure conditions and materials exposed to in-service conditions is given, and a validation is presented for the methodology based upon durability test results for PVC and coPC.     

On the Locus of Speed-Accuracy Trade-Off in Reaction Time: Inferences From the Lateralized Readiness Potential.

Lateralized readiness potentials (LRPs) were used to determine the stage(s) of reaction time (RT) responsible for speed-accuracy trade-offs (SATs). Speeded decisions based on several types of information were examined in 3 experiments, involving, respectively, a line discrimination task, lexical decisions, and an Erikson flanker task. Three levels of SAT were obtained in each experiment by adjusting response deadlines with an adaptive tracking algorithm. Speed stress affected the duration of RT stages both before and after the start of the LRP in all experiments. The latter effect cannot be explained by guessing strategies, by variations in response force, or as an indirect consequence of the pre-LRP effect. Contrary to most models, it suggests that SAT can occur at a late postdecisional stage. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Personalisierung und informationelle Selbstbestimmung Ein unauflösbarer Widerspruch?

Ohne Zusammenfassung     

3D Micro-PIXE at atmospheric pressure: A new tool for the investigation of art and archaeological objects

The paper describes a novel experiment characterized by the development of a confocal geometry in an external Micro-PIXE set-up. The position of X-ray optics in front of the X-ray detector and its proper alignment with respect to the proton micro-beam focus provided the possibility of carrying out 3D Micro-PIXE analysis. As a first application, depth intensity profiles of the major elements that compose the patina layer of a quaternary bronze alloy were measured. A simulation approach of the 3D Micro-PIXE data deduced elemental concentration profiles in rather good agreement with corresponding results obtained by electron probe micro-analysis from a cross-sectioned patina sample. With its non-destructive and depth-resolving properties, as well as its feasibility in atmospheric pressure, 3D Micro-PIXE seems especially suited for investigations in the field of cultural heritage.     

A Study of Surface Deformation during Wire‐Rod Rolling of High Speed Steels using Experimental and Computational Techniques

The evolution of surface defects during shape rolling of high‐speed steel billets is studied using longitudinal surface defects prepared by machining and welding. The reduction of the defects during rolling in a production mill is compared to the total area reduction of the billets. Samples are collected after pass 4, 6, 8, 14, 19 and the final pass, 28, representing the finished 5.5mm wire. By inspecting the cross sections, the rotation of the billets from pass to pass is evaluated. Results from FE simulations on solid billets are compared to the experimental results. Generally, simulations predict less reduction than observed experimentally. In most cases cracks reduce most effectively followed by carbon steel welds and stainless steel welds.     

Cathodic reduction of acids in dimethylformamide on platinum

A linear correlation was shown to exist between the acidity and the cyclic voltammetric half-potential of the reduction of acids in DMF for carboxylic and N-acids in the pK_a range of 6-16. Chlorophenols are reduced at slightly lower potentials giving a separate parallel line. Applying the obtained equation and employing the same method to literature data in DMSO, the pK_a values for conjugate aids of DMF and DMSO can be calculated, showing DMSO·H⁺ to be more acidic (pK_a = 2.9) than DMF·H⁺ (pK_a = 5.7). The analysis of cyclovoltammetric data demonstrated that a CE mechanism operates in the reduction of strong acids, including the conjugate acid of DMF. Weaker acids are reduced by direct discharge or a mixed mechanism.     

Gelation and phase separation in maltodextrin-caseinate systems

A range of rheological techniques, including small deformation isothermal runs following quenching, controlled rate heating profiles, mechanical spectra, and large deformation strain sweeps and creep compliance testing, were employed in the investigation of maltodextrin—sodium caseinate aqueous dispersions. The concentration dependence, viscoelastic ratio and melting profiles of shear moduli for concentrated maltodextrin samples suggest a highly aggregated, enthalpically linked biopolymer gel. By contrast, the caScinate particles form a ‘pasty’ solid at low temperatures with a high viscous component, which upon moderate heating reverts readily into an entropically driven liquid body. Mixing of the polymers results in a composite system whose phase inversion from a maltodextrin continuous network with discontinuous protein inclusions to a caScinate dispersion suspending the polysaccharide particles is determined by the weight ratio of the two components in the blend. The overall strength of the composite has been related to the mechanical functions of the individual components, and the idea of kinetically trapped mixed gels has been put forward to rationalize the solvent partition between the two constituent phases. Results were used to advance the conclusions reached from work on other mixed biopolymer systems carried out in this laboratory.